| Autor: |
Henry, Hakeem K., Johnston, Brandon, Liau, Darrin, Sahadeo, Emily, Leez, Sang Bok |
| Předmět: |
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| Zdroj: |
Journal of The Electrochemical Society; Aug2020, Vol. 167 Issue 11, p1-6, 6p |
| Abstrakt: |
In recent years there has been some discrepancy about whether crystalline or amorphous V2O5 is the superior cathode material for magnesium-ion batteries, with many publications suggesting that amorphous V2O5more readily stores magnesium ions. In this work, we report the systematic investigation of magnesium ion storage in crystalline and amorphous V2O5electrodeposited thin films. Our results indicate that the electrochemical performance of V2O5thin films is primarily impacted by the presence of adsorbed water. This study finds that the adsorbed water left over from aqueous electrodeposition is mostly responsible for the observed improved performance of amorphous V2O5thin films, thereby indicating that the drying conditions, rather than the crystal structure, play a direct role in enhancing the electrochemical performance. We propose an explanation for this observation in that the amorphous thin film has much larger water content, leading to increased interlayer spacing within the disordered structure and possible charge shielding for magnesium-ion storage. Ultimately, this study demonstrates the importance of considering the effect of adsorbed water, especially when comparing the electrochemical performance of amorphous and crystalline V2O5synthesized from wet electrodeposition techniques. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Supplemental Index |
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