| Autor: |
Dunlap, Nathan Arthur, Jongbeom Kim, Guthery, Harvey, Chun-Sheng Jiang, Morrissey, Ian, Stoldt, Conrad R., Kyu Hwan Oh, Al-Jassim, Mowafak, Se-Hee Lee |
| Předmět: |
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| Zdroj: |
Journal of The Electrochemical Society; Apr2020, Vol. 167 Issue 6, p1-7, 7p |
| Abstrakt: |
A slurry-coated sheet-style Si-based anode is developed for use in all-solid-state Li-ion batteries. Inexpensive, mixed-conducting polyacrylonitrile (PAN) is utilized as both binder and conductive additive, enabling Si-rich electrodes (70 wt%) to attain large reversible capacities ∼1,500 mAh g−1 (Si) at 1 C rates (>3 mA cm−2 ). Cross sectional analysis of a discharged all-solid-state halfcell indicates that the Si-PAN anode achieves the largest volumetric specific capacity ever reported for a Li-ion electrode (>1500 mAh cm−3 ). Ex situ Raman spectroscopic studies reveal that the anodes’ reversibility is attributed to the preservation of small tetrahedrally coordinated clusters within their Si nanoparticles upon discharge. We therefore argue that careful lithiation limitations should be implemented in all Si-based Li-ion anodes to preserve this local tetrahedral atomic structure. The slurry-coated sheetstyle Si-PAN anodes have been successfully cycled in all-solid-state full-cells against high-voltage nickel-rich NMC 811 composite cathodes to encourage future commercialization of similar sheet-style all-solid-state designs. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Supplemental Index |
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