| Autor: |
Akane Enomoto, Shunpei Kajita, Ken-ichi Fujita |
| Zdroj: |
Chemistry Letters; Feb2019, Vol. 48 Issue 2, p106-109, 4p |
| Abstrakt: |
A new protocol for the production of deuterium gas from easily-obtainable deuterated methanol and deuterium oxide has been developed. The reaction of deuterated methanol and deuterium oxide in the presence of an iridium catalyst bearing a functional bipyridonate ligand and sodium hydroxide under reflux for 48 hours gave deuterium gas in 63% yield. Deuteration reactions of unsaturated compounds and bromosubstituted aromatic compounds using the generated deuterium gas in the presence of palladium/charcoal catalyst were also investigated. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Supplemental Index |
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