A Molecular Conductor Based on Axially CN-Substituted Cobalt Tetrabenzoporphyrin.

Autor: Masaki Matsuda, Hiroko Ohishi, Madoka Tofuku, Naho Muramoto, Jun-ichi Yamaura
Zdroj: Chemistry Letters; 11/5/2011, Vol. 40 Issue 11, p1257-1259, 3p
Abstrakt: A molecular conductor based on axially CN-substituted cobalt tetrabenzoporphyrin is reported. The crystal structure is isomorphous with a phthalocyanine-based conductor, however, estimation of effectiveness of π π overlap and electrical transport measurement reveal that a slight change in molecular structure of macrocyclic π-conjugated ligands has significant influence on intermolecular interaction and electrical properties. [ABSTRACT FROM AUTHOR]
Databáze: Supplemental Index