Addition of N-Acyliminium Ion Pools to Alkenes Having a Nucleophilic Moiety: Integration of Intermolecular and Intramolecular Reactions.

Autor: Yosuke Ashikari, Yohei Kiuchi, Tomoya Takeuchi, Koji Ueoka, Seiji Suga, Jun-ichi Yoshida
Zdroj: Chemistry Letters; 2/5/2014, Vol. 43 Issue 2, p210-212, 3p
Abstrakt: The reaction of electrochemically generated N-acyliminium ion pools with alkenes bearing a heteroatom nucleophilic functionality such as a hydroxy group, a carboxy group, and an oxime moiety led to intermolecular carboncarbon bond formation followed by intramolecular carbonheteroatom bond formation to give the corresponding heterocyclic compounds such as cyclic ethers, lactones, and 2-isoxazolines, respectively. [ABSTRACT FROM AUTHOR]
Databáze: Supplemental Index