| Autor: |
Toru Kuwano, Takuya Kurahashi, Seijiro Matsubara |
| Zdroj: |
Chemistry Letters; 10/5/2013, Vol. 42 Issue 10, p1241-1243, 3p |
| Abstrakt: |
We have developed cationic iron(IV) corrole-catalyzed formal hetero-Diels-Alder reaction of aldehydes with dienes, which opens the way for divergent synthesis of pyrans. The potential utility of the catalyst was also demonstrated by carrying out cycloaddition of α,β-unsaturated aldehyde with a diene to give pyran selectively. Furthermore, the catalytic reactivity of iron corrole complex on the cycloaddition was determined by comparing that of iron porphyrin complex. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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