A semi-automated Raman micro-spectroscopy method for morphological and chemical characterizations of microplastic litter.

Autor: L., Frère, I., Paul-Pont, J., Moreau, P., Soudant, C., Lambert, A., Huvet, E., Rinnert
Předmět:
Zdroj: Marine Pollution Bulletin; Dec2016, Vol. 113 Issue 1/2, p461-468, 8p
Abstrakt: Every step of microplastic analysis (collection, extraction and characterization) is time-consuming, representing an obstacle to the implementation of large scale monitoring. This study proposes a semi-automated Raman micro-spectroscopy method coupled to static image analysis that allows the screening of a large quantity of microplastic in a time-effective way with minimal machine operator intervention. The method was validated using 103 particles collected at the sea surface spiked with 7 standard plastics: morphological and chemical characterization of particles was performed in < 3 h. The method was then applied to a larger environmental sample ( n = 962 particles). The identification rate was 75% and significantly decreased as a function of particle size. Microplastics represented 71% of the identified particles and significant size differences were observed: polystyrene was mainly found in the 2–5 mm range (59%), polyethylene in the 1–2 mm range (40%) and polypropylene in the 0.335–1 mm range (42%). [ABSTRACT FROM AUTHOR]
Databáze: Supplemental Index