One-Nanometer-Precision Control of Al2O3 Nanoshells through a Solution-Based Synthesis Route.

Autor: Zhang, Wei, Chi, Zi-Xiang, Mao, Wen-Xin, Lv, Rong-Wen, Cao, An-Min, Wan, Li-Jun
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Zdroj: Angewandte Chemie; Nov2014, Vol. 126 Issue 47, p12990-12994, 5p
Abstrakt: Forming uniform metal oxide nanocoatings is a well-known challenge in the construction of core-shell type nanomaterials. Herein, by using buffer solution as a specific reaction medium, we demonstrate the possibility to grow thin nanoshells of metal oxides, typically Al2O3, on different kinds of core materials, forming a uniform surface-coating layer with thicknesses achieving one nanometer precision. The application of this methodology for the surface modification of LiCoO2 shows that a thin nanoshell of Al2O3 can be readily tuned on the surface for an optimized battery performance. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index