Homeotropic alignment and Förster resonance energy transfer: The way to a brighter luminescent solar concentrator.

Autor: Tummeltshammer, Clemens, Taylor, Alaric, Kenyon, Anthony J., Papakonstantinou, Ioannis
Předmět:
Zdroj: Journal of Applied Physics; 2014, Vol. 116 Issue 17, p173103-1-173103-8, 8p, 1 Diagram, 2 Charts, 8 Graphs
Abstrakt: We investigate homeotropically aligned fluorophores and Förster resonance energy transfer (FRET) for luminescent solar concentrators using Monte-Carlo ray tracing. The homeotropic alignment strongly improves the trapping efficiency, while FRET circumvents the low absorption at homeotropic alignment by separating the absorption and emission processes. We predict that this design doped with two organic dye molecules can yield a 82.9% optical efficiency improvement compared to a single, arbitrarily oriented dye molecule. We also show that quantum dots are prime candidates for absorption/donor fluorophores due to their wide absorption band. The potentially strong re-absorption and low quantum yield of quantum dots is not a hindrance for this design. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index