Size selected synthesis of CoFe2O4 nanoparticles prepared in a chitosan matrix.

Autor: Gurgel, A. L., Soares, J. M., Chaves, D. S., Xavier Jr., M. M., Morales, M. A., Baggio-Saitovitch, E. M.
Předmět:
Zdroj: Journal of Applied Physics; May2010, Vol. 107 Issue 9, p09A746-1-09A746-3, 3p
Abstrakt: In this paper we report the synthesis and magnetic properties of CoFe2O4 nanoparticles. The nanoparticles with sizes ranging from 6 to 20 nm were prepared in a chitosan matrix. Size selection was achieved by introducing a nonionic surfactant Tween-X, where X={20, 60, 80, and 85}. Aqueous dispersions of Tween-X show micelles with increasing hydrodynamic sizes as X increases. Mössbauer spectroscopy measurements at 300 K show superparamagnetic behavior for the small particles, changing gradually to a blocked magnetic regime as the particle size increases. Magnetization measurements at 300 K show increasing values for the ratio Mr /MHmax and coercive fields (Hc). [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index