Synthesis and characterization of poly(2,5-didecyl-1,4-phenylene vinylene), poly(2,5-didecyloxy-1,4-phenylene vinylene), and their alternating copolymer.

Autor:	Young, Crystal A., Saowsupa, Sairoong, Hammack, Audrey, Tangonan, Andrew A., Anuragudom, Piched, Jia, Huiping, Jamison, Andrew C., Panichphant, Sukon, Gnade, Bruce E., Lee, T. Randall
Předmět:	COPOLYMERIZATION PHENYLENE compounds HORNER-Emmons reaction POLYCONDENSATION ORGANIC light emitting diodes
Zdroj:	Journal of Applied Polymer Science; Dec2014, Vol. 131 Issue 23, pn/a-N.PAG, 12p
Abstrakt:	ABSTRACT The preparation of dialkyl-substituted poly(2,5-didecyl-1,4-phenylene vinylene) ( PDDPV) by the Horner-Emmons polycondensation is described. Its performance in an organic light-emitting diode (OLED) device architecture is compared with devices prepared from the analogous dialkoxy-substituted poly(2,5-didecyloxy-1,4-phenylene vinylene) ( PDOPV) and the corresponding alkyl-alkoxy-substituted alternating copolymer. Additionally, the structure, stability, electrochemical, and optical properties of the PPVs were characterized by gel permeation chromatography, thermogravimetric analysis, NMR spectroscopy, cyclic voltammetry, UV-Visible spectroscopy, and fluorescence spectroscopy. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014, 131, 41162. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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