Ligand-Assisted Copper-Catalyzed Oxidative Cross-Coupling of Simple Phenols with Formamides for the Synthesis of Carbamates.

Autor: Veera Reddy, Nagireddy, Kumar, Gadde Sathish, Kumar, Pailla Santhosh, Kantam, M. Lakshmi, Reddy, Kallu Rajender
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Zdroj: Synlett; 2014, Vol. 25 Issue 15, p2133-2138, 6p
Abstrakt: An oxidative approach for the synthesis of phenyl carbamates has been achieved by ligand-assisted copper-catalyzed crossdehydrogenative coupling (CDC) of phenols with formamides. The direct coupling of simple phenols with mono- and dialkyl formamides provides carbamate products in moderate to good yields under mild reaction conditions. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index