| Autor: |
Engin, Selma, Sisourat, Nicolas, Selles, Patricia, Taïeb, Richard, Carniato, Stéphane |
| Předmět: |
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| Zdroj: |
Journal of Chemical Physics; 6/21/2014, Vol. 140 Issue 23, p234303-1-234303-10, 10p, 9 Graphs |
| Abstrakt: |
Raman Chirped Adiabatic Passage (RCAP) is an efficient method to climb the vibrational ladder of molecules. It was shown on the example of fixed-in-space HCl molecule that selective vibrational excitation can thus be achieved by RCAP and that population transfer can be followed by X-ray Photoelectron spectroscopy [S. Engin, N. Sisourat, P. Selles, R. Taïeb, and S. Carniato, Chem. Phys. Lett. 535, 192-195 (2012)]. Here, in a more detailed analysis of the process, we investigate the effects of highly excited electronic states and of molecular rotation on the efficiency of RCAP. Furthermore, we propose an alternative spectroscopic way to monitor the transfer by means of X-ray absorption spectra. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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