Two new cyano-bridged Cu(II)-Fe(II) complexes: Synthesis and crystal structures.

Autor:	Tang, M., Liu, J., Chen, W., Yang, Y., Ren, S.
Předmět:	COPPER compounds synthesis METAL complexes CRYSTAL structure X-ray crystallography OCTAHEDRA GEOMETRIC analysis
Zdroj:	Russian Journal of Coordination Chemistry; Jun2014, Vol. 40 Issue 6, p419-423, 5p
Abstrakt:	Two new cyano-bridged Cu(II)-Fe(II) binuclear complexes, [Cu(L)Fe(CN)(NO)] ( I) [L = 1,3,6,8,11,14-hexaazatricyclo[12.2.1.1]octadecane and [Cu(L)Fe(CN)(NO)] · 2HO ( II) L = 1,3,6,9,11,14-hexaazatricyclo[12.2.1.1]octadecane, have been assembled and structurally characterized by spectroscopy and X-ray crystallography. Complex I crystallizes in the monoclinic crystalline system of space group P2/ c, while complex II crystallizes in the monoclinic crystalline system of space group P2/ n. These two complexes assume a binuclear structure in which the Fe ion is in an octahedron environment and the Cu ion is in a square-prism geometry environment. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
Externí odkaz:	Zobrazit plný text záznamu Full text from SpringerLink