Selective synthesis of cyclododec-2-en-1-yl ethers via palladium-catalyzed allylic substitution reaction: a kinetic study.

Autor: KOLEV, Asen, MITKOVA, Magdalena, KOTOV, Stefan, BALBOLOV, Encho
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Zdroj: Turkish Journal of Chemistry; Apr2014, Vol. 38 Issue 2, p242-247, 6p
Abstrakt: The palladium-catalyzed reaction between isomeric cyclododec-2-en-1-yl acetates and primary aliphatic alcohols was found to result in high yields of the reaction products obtained. The selectivity with respect to cyclododec-2-en-1-yl ethers formed as reaction products ranged from 73% to 93%. The kinetics of the reaction of acetoxycyclododec-2-enes with alcohols was studied within the temperature range of 328-358 K. A kinetic equation best fitting the experimental data was provided. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index