Experimental and Theoretical Study of Electroluminescence Spectra of the Light-Emitting Devices Based on Zinc Complexes of Amino-Substituted Ligands.

Autor: Krasnikova, S. S., Shestakov, A. F., Kaplunov, M. G.
Předmět:
Zdroj: Molecular Crystals & Liquid Crystals; Jan2014, Vol. 589 Issue 1, p56-66, 11p
Abstrakt: The electroluminescence spectra of the light-emitting devices based on two zinc complexes of amino-substituted ligands Zn(DFP-SAMQ)2and Zn(PSA-BTZ)2are studied. The intrinsic and exciplex bands are observed in the spectra, the relation between them being strongly dependent on the material of a hole-transporting layer. A quantum-chemical study of the spectral properties of these complexes and the light-emitting devices based on them using the PBE density functional method is made. To model the spectra of a device, the spectra of the adduct containing one molecule of the zinc complex and one molecule of the hole-transporting material are calculated. The accordance between the experimental and theoretical data is observed. [ABSTRACT FROM PUBLISHER]
Databáze: Complementary Index