A Direct, Modular, and Efficient Construction of the PCP Structural Motif through Coupling of Manganese Carbyne Complexes with Phosphines.

Autor: Valyaev, Dmitry A., Bastin, Stéphanie, Utegenov, Kamil I., Lugan, Noël, Lavigne, Guy, Ustynyuk, Nikolai A.
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Zdroj: Chemistry - A European Journal; Feb2014, Vol. 20 Issue 8, p2175-2178, 4p
Abstrakt: Easily available carbyne complexes of manganese were used as a source of carbyne fragments in an unconventional synthesis of backbone-substituted diphosphinomethanes and cyclic P-ylides upon coupling with secondary or tertiary phosphines, respectively, followed by demetalation under mild conditions. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index
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