Synthesis, mechanism of formation and spatial arrangement of (2 S,3 S,6 R)-2,6-diphenyl-3,4-dimethyl-6-ol.

Autor: Nurkenov, O., Fazylov, S., Abulyaissova, L., Turdybekov, K., Shaltakov, S., Isaeva, A.
Předmět:
Zdroj: Russian Journal of General Chemistry; Dec2013, Vol. 83 Issue 12, p2276-2280, 5p, 5 Diagrams, 3 Charts
Abstrakt: Alkylation of alkaloid D-pseudoephedrine with bromoacetophenone results in a morpholine derivative. Structural and energy characteristics of the molecules of the starting, intermediate, and final reaction products were calculated by ab initio method in the HF/6-31G(d,p) approximation. The spatial structure of the final reaction product was determined by X-ray diffraction analysis. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index