| Autor: |
Audier, Henri Edouard, Milliet, Arielle, Sozzi, Georges, Hammerum, Steen |
| Zdroj: |
Organic Mass Spectrometry; 1990, Vol. 25 Issue 1, p44-48, 5p |
| Abstrakt: |
The key intermediates to the fragmentation of metastable methyl and ethyl benzoate radical cations are α- and β-distonic isomers of the molecular ions. The α-distocic isomers are also formed by fragmentation of longer chain alkyl benzoates, but may not be long-lived, stable species. Rearrangement of the α-distonic ions prior to fragmentation can take place, but (re)formation of the benzoate molecular ions does not occur. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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