| Autor: |
Lay, Jackson O., Allison, Neil T., Yongskulrote, W., Ferede, R. |
| Zdroj: |
Organic Mass Spectrometry; 1986, Vol. 21 Issue 6, p371-374, 4p |
| Abstrakt: |
The high resolution mass spectra of five novel η1-R substituted Fe(II)(CO)2 η5-C5H5 complexes are reported. Fragmentation behavior common to all the studied compounds is noted, as well as some ligand-specific fragmentation. Fragment ions associated with ligand recoordination, ligand substituent transfer and inter-ligand bond formation are noted. The role of the electron density around the metal center, and in particular the '18-electron' configuration, on the fragmentation of these compounds is discussed. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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