Energy partitioning in the metastable fragmentation [C3H7]+ → [C3H5]+ + H2.

Autor: Holmes, John L., Osborne, Alexander D.
Zdroj: Organic Mass Spectrometry; 1978, Vol. 13 Issue 3, p133-134, 2p
Abstrakt: The dish-topped metastable peak for the fragmentation [C3H7]+ → [allyl]+ + H2 is generated by the threshold fragmentation. The fraction of the reverse activation energy which is partitioned as translational energy of the products is 0.9 ± 0.1. It is proposed that a similar partitioning coefficient applies to the excess internal energy above threshold. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index