Internal energy effects on the mass spectral fragmentations of some phosphorus heterocycles.

Autor: Weringa, W. D., Granoth, I.
Zdroj: Organic Mass Spectrometry; 1973, Vol. 7 Issue 4, p459-461, 3p
Abstrakt: In addition to the elimination of C6H5· and C7H7·, 2,8-dimethyl-10-phenyl- and 10-( p-tolyl)-phenothiaphosphines lost C6H5S· and C7H7S·, respectively from high internal energy molecular ions, while the low internal energy ions eliminated C6H5PH and C7H7PH, respectively. 2,8-Dimethyl-10-phenylphenoxaphosphine lost C6H5·, C6H5P and C6H5PH· both in the source and in the first field-free region, but the expulsion of C6H5O· was not observed. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index