| Autor: |
Granoth, I., Kalir, A., Pelah, Z., Bergmann, E. D. |
| Zdroj: |
Organic Mass Spectrometry; 1970, Vol. 3 Issue 11, p1359-1364, 6p |
| Abstrakt: |
The molecular ion of the phenothiaphosphine derivatives is fairly stable. Under electronimpact, the phenothiaphosphines (I) and phenothiaphosphinic acids (IV, R = H) undergo a one-step elimination of the phosphorus atom together with the groups attached to it. Substitutents in the aromatic rings, as well as on the phosphorus, influence the fragmentation pattern; ring methyl, e.g. leads to tropylium structures. Phosphine oxides of type V lose RO˙, probably after a rearrangement, when R = aryl, but R˙ if it is methyl. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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