Atoms state and interatomic interactions in perovskite-like oxides: XXXII. Formation of paramagnetic clusters in the LaCaFeAlO and LaSrFeAlO solid solutions.

Autor: Chezhina, N., Fedorova, A., Musatov, S.
Předmět:
Zdroj: Russian Journal of General Chemistry; Sep2013, Vol. 83 Issue 9, p1645-1648, 4p
Abstrakt: Calcium- and strontium-containing lanthanum orthoferrites have been studied using magnetic dilution method. It has been shown that the iron-atom clusters with competing ferro- and antiferromagnetic exchange interactions can exist. By using Mossbauer spectroscopy, Fe(IV) atoms have been found in the LaCaFeAlO solid solutions and Fe(III) atoms in two different surroundings have been found in the LaSrFeAlO solid solutions. The compositions of paramagnetic clusters stable at the infinite dilution have been proposed basing of the magnetic susceptibility and Mossbauer spectroscopy data. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index