T( x) phase diagram of the CuSbS2-CuInS2 system and solubility limit of Sb in CuInS2.

Autor: Korzun, B. V., Gavrilenko, A. N., Fadzeyeva, A. A., Ignatenko, O. V., Maroz, I. I., Sobol, V. R., Rusu, M., Klenk, R., Merschjann, C., Schedel‐Niedrig, Th., Lux‐Steiner, M. Ch.
Zdroj: Crystal Research & Technology; Sep2013, Vol. 48 Issue 9, p641-648, 8p
Abstrakt: The starting ternary compounds CuInS2 and CuSbS2 and alloys of the CuSbS2-CuInS2 system with the molar fractions of CuInS2 ( x) equal to 0.05, 0.15, 0.25, 0.375, 0.50, 0.625, 0.75, 0.85, and 0.95 were prepared and the phase relations in this system were investigated by X-ray powder diffraction, optical microscopy, scanning electron microscopy, and differential thermal analysis. It was shown that the T-x phase diagram of the CuInS2-CuSbS2 system has a eutectic character with the eutectic temperature of 807 K. The alloys of the CuSbS2-CuInS2 system with the molar fraction of CuInS2 in the range from 0.038 to 0.941 at room temperature are two-phased, and the limits of solubility are 0.059 molar fractions for CuSbS2 in CuInS2 and 0.038 molar fractions for CuInS2 in CuSbS2. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index