| Autor: |
Wang, Chubei, Zhou, Jianwei, Lv, Xingbin, Wen, Junlei, He, Hongwu |
| Předmět: |
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| Zdroj: |
Phosphorus, Sulfur & Silicon & the Related Elements; Oct2013, Vol. 188 Issue 10, p1334-1339, 6p |
| Abstrakt: |
A new, environmentally benign, convenient, and easy method of synthesizing tertiary α-hydroxyphosphonates by the triethylamine-catalyzed hydrophosphonylation of unactivated ketones was developed. In the presence of triethylamine, aromatic or heteroaromatic ketones can react with phosphite to form tertiary α-hydroxyphosphonates under solvent-free and mild conditions. The proposed method was also suitable for functionalized ketones. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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