Iron-Salt-Promoted Highly Regioselective α and β Hydrophosphination of Alkenyl Arenes.

Autor:	Routaboul, Lucie, Toulgoat, Fabien, Gatignol, Jérémie, Lohier, Jean‐François, Norah, Brigitte, Delacroix, Olivier, Alayrac, Carole, Taillefer, Marc, Gaumont, Annie‐Claude
Předmět:	REGIOSELECTIVITY (Chemistry) STYRENE DIPHENYLPHOSPHINE ORGANIC synthesis TRANSITION metals
Zdroj:	Chemistry - A European Journal; Jul2013, Vol. 19 Issue 27, p8760-8764, 5p
Abstrakt:	Iron(ic) phosphination: The iron‐promoted hydrophosphination of alkenyl arenes with diphenylphosphine as the phosphinating agent has been established. This method provides efficient access to diarylalkylphosphines. The regioselectivity of the reaction can be fine‐tuned by the choice of the iron salts, offering highly selective access to both the β and the α adducts (see scheme). [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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