Synthesis of an Azahomoazafullerene C59N(NH)R and Gas-Phase Formation of the Diazafullerene C58N2.

Autor: Huang, Huan, Zhang, Gaihong, Wang, Dian, Xin, Nana, Liang, Sisi, Wang, Nengdong, Gan, Liangbing
Zdroj: Angewandte Chemie International Edition; May2013, Vol. 52 Issue 19, p5037-5040, 4p
Abstrakt: Open the cage if you dare: The azahomoazafullerene 1 was prepared from a tert‐butylperoxy‐substituted azafullerene derivative C59NBr(OOtBu)4. Singlet oxygen added to 1 to form an open‐cage azafullerene 2 with a ketoimide moiety on the rim of the orifice. The MALDI‐TOF mass spectrum of the product of the hydrolysis of 1 showed a clear signal for the diazafullerene C58N2 (see structure 3). [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index