Autor: |
Huang, Huan, Zhang, Gaihong, Wang, Dian, Xin, Nana, Liang, Sisi, Wang, Nengdong, Gan, Liangbing |
Zdroj: |
Angewandte Chemie International Edition; May2013, Vol. 52 Issue 19, p5037-5040, 4p |
Abstrakt: |
Open the cage if you dare: The azahomoazafullerene 1 was prepared from a tert‐butylperoxy‐substituted azafullerene derivative C59NBr(OOtBu)4. Singlet oxygen added to 1 to form an open‐cage azafullerene 2 with a ketoimide moiety on the rim of the orifice. The MALDI‐TOF mass spectrum of the product of the hydrolysis of 1 showed a clear signal for the diazafullerene C58N2 (see structure 3). [ABSTRACT FROM AUTHOR] |
Databáze: |
Complementary Index |
Externí odkaz: |
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