Copolymerization of indene with dicyclopentadiene under the action of the catalyst system TiCl4-AlEt2Cl.

Autor: Lyapkov, A. A., Ionova, E. I., Zyabbarova, E. B., Bondaletov, V. G.
Zdroj: 2012 7th International Forum on Strategic Technology (IFOST); 1/ 1/2012, p1-4, 4p
Abstrakt: Copolymerization of indene and dicyclopentadiene was studied in toluene solution under the action of the catalyst system Et2AlCl-TiCl4. It is established that in this case alternating copolymers formed, and the dicyclopentadiene is more active monomer in the mixture. It is concluded that the ratio of dicyclopentadiene to indene equal 0.58:0.42 corresponds to the azeotropic point in the curve of the copolymer, as well as the heat dissipation in the system extremely dependent on the content of dicyclopentadiene in the copolymer. [ABSTRACT FROM PUBLISHER]
Databáze: Complementary Index