Autor: |
Arredondo, M., Weyland, M., Hambe, M., Ramasse, Q. M., Munroe, P., Nagarajan, V. |
Předmět: |
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Zdroj: |
Journal of Applied Physics; Apr2011, Vol. 109 Issue 8, p084101, 8p |
Abstrakt: |
We investigate the interfacial structure of PbZr0.20Ti0.80O3 (PZT)/La0.67Sr0.33MnO3 (LSMO)/SrTiO3 heterostructures by combining low-magnification transmission electron microscopy imaging and spectroscopy techniques with high-resolution spherical-aberration corrected scanning transmission electron microscopy imaging, geometrical phase analysis, and spectroscopy results. For certain thickness regimes, the interface between PZT and LSMO is found to have a significant density of planar defects at the interface. Both A-site cation (Pb) diffusivity and highly inhomogeneous local strains are observed at the boundaries of the defect areas. It is proposed that Pb is incorporated as PbO Ruddlesden-Popper planar fault within the LSMO. These results underline the importance of chemical fluctuations caused by long-range strain fields associated with defect cores. [ABSTRACT FROM AUTHOR] |
Databáze: |
Complementary Index |
Externí odkaz: |
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