| Autor: |
Yanagisawa, Akira, Jitsukawa, Takuya, Yoshida, Kazuhiro |
| Předmět: |
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| Zdroj: |
Synlett; 3/15/2013, Vol. 24 Issue 5, p635-639, 5p |
| Abstrakt: |
The addition of allylic barium reagents to azo compounds was achieved with high α-regioselectivity. The double-bond geometry of allylic barium reagents was retained throughout the reaction at -78 °C and E- or Z-enriched allylic hydrazines were selectively obtained from the corresponding allylic barium reagents. An allylic hydrazine was efficiently converted into an allylic amine by reductive N-N bond cleavage. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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