| Autor: |
Blanquet, G., Walrand, J., Bouanich, J. -P., Boulet, C. |
| Předmět: |
|
| Zdroj: |
Journal of Chemical Physics; 11/15/1990, Vol. 93 Issue 10, p6962, 9p |
| Abstrakt: |
The spectra of several Ar-broadened symmetric doublets in the hot band ν1+ν2-ν2 (at 850 cm-1) of OC 32S have been recorded with a tunable diode-laser spectrometer. The pressure-broadening coefficients measured for sufficiently separated lines belonging to 7 doublets are in agreement with the results previously obtained in the ν1 band. From these data, we have determined, for different pressures of argon, line-coupling coefficients for 15 doublets in the P and R branches of the hot band. These coefficients appear to be small and negative, at the limit of our estimated accuracy, which implies very weak line-mixing effects in the doublets, in agreement with the results of a semiclassical calculation as well as with results of coupling cross sections estimated at large-j values from the infinite order sudden (IOS) approximation. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
|
