Photodetachment of WO-3: The electron affinity of WO3.

Autor: Walter, C. W., Hertzler, C. F., Devynck, P., Smith, G. P., Peterson, J. R.
Předmět:
Zdroj: Journal of Chemical Physics; 7/15/1991, Vol. 95 Issue 2, p824, 4p
Abstrakt: Photodetachment cross sections for WO-3 have been measured near the detachment threshold (3.0–3.7 eV). A fast beam of WO-3 is merged with a coaxial cw laser beam and the photodetached electrons are detected with a magnetic confinement slow electron collector. The photodetachment spectrum yields an electron affinity for WO3 of 3.33+0.08-0.15 eV, somewhat lower than values obtained in thermodynamic equilibrium measurements. In addition, a lower limit of 3.7 eV is obtained for the electron affinity of HWO4. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index