Optical emission spectra of Ag3 molecules in the gas evaporation technique.

Autor: Okazaki, Tsugio, Saito, Yahachi, Kasuya, Atsuo, Nishina, Yuichiro
Předmět:
Zdroj: Journal of Chemical Physics; 1/15/1996, Vol. 104 Issue 3, p812, 3p
Abstrakt: A study was conducted of optical emission spectra, taken at a region near the source of the evaporation of Ag in a low pressure helium gas (100 Torr). A new Ag3 emission band system was identified. Spectroscopic constants for an excited and a lower state (the ground state) in the gas phase were derived as follows: ν00=19 809.4±2.0 cm-1, ω′1=106.8±1.0 cm-1, x′11=-0.2±0.5 cm-1, ω″1=129.0±1.0 cm-1, and x″11=-0.1±0.5 cm-1 for the 107Ag2109Ag trimers. Spectroscopic constants for three other isotope species were also derived. The lower state was the 2B2 ground state. © 1996 American Institute of Physics. [ABSTRACT FROM AUTHOR]
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