Self-collisional coupling and broadening in the asymmetric rotor CHF2Cl.

Autor: Cazzoli, G., Cludi, L., Cotti, G., Esposti, C. Degli, Buffa, G., Tarrini, O.
Předmět:
Zdroj: Journal of Chemical Physics; 1/15/1995, Vol. 102 Issue 3, p1149, 8p
Abstrakt: The line shape of 15 selected CHF2Cl rotational transitions is studied in the 59–1049 GHz frequency region. Collisional broadening parameters are measured and compared to semiclassical calculations. For some pairs of lines a large collisional coupling effect is observed and analyzed. A semiclassical theoretical model is presented allowing calculations of the coupling parameters in good agreement with measurements. © 1995 American Institute of Physics. [ABSTRACT FROM AUTHOR]
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