Photostimulated synchronous chlorination of polymers at low temperatures.

Autor: Kuzina, S., Kozlovskii, A., Mikhailov, A.
Zdroj: Russian Chemical Bulletin; Sep2011, Vol. 60 Issue 9, p1927-1932, 6p
Abstrakt: High yields of free radicals (10-10 spin g) were found upon the low-temperature (77 K) chlorination of solid synthetic polymers on irradiation with light with λ ≥ 360 nm. The stage of radical formation was considered in the framework of the mechanism of concerted reactions in the polymolecular complex [polymer-Cl]. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index