First gas phase spectrum of the aluminum carbide molecule: The B 4Σ-–X 4Σ- system.

Autor: Brazier, C. R.
Předmět:
Zdroj: Journal of Chemical Physics; 2/15/1993, Vol. 98 Issue 4, p2790, 8p, 6 Charts, 2 Graphs
Abstrakt: The aluminum carbide radical has been seen in the gas phase for the first time. The B 4Σ-–X 4Σ- system near 22 000 cm-1 was observed in emission from a hollow cathode source. Three vibrational sequences were detected: Δv=0, -1, and -2, and a full rotational analysis was performed on the five strongest bands, 0-0, 1-1, 0-1, 1-2, and 2-3. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index