| Autor: |
Shen, L. N., Withey, P. A., Graham, W. R. M. |
| Předmět: |
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| Zdroj: |
Journal of Chemical Physics; 2/15/1991, Vol. 94 Issue 4, p2395, 6p |
| Abstrakt: |
An absorption has been detected at 1699.8 cm-1 in the midinfrared spectrum of the vacuum ultraviolet photolysis products of 1,3-butadiene (C4H6) trapped in Ar at 10 K, which on the basis of extensive13 C-substitution experiments is shown to belong to the C4 carbon chain. The behavior of the new band correlates closely with the ν2, C[larger_closed_square]C stretching vibration of linear C4 at 1543.4 cm-1 identified in an earlier paper. It is argued that the 1699.8 cm-1 absorption is a combination band involving the C[larger_closed_square]C stretching vibration and a bending mode of C4, with a cis-bent structure. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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