Heats of transport from diffusion thermoeffect measurements on binary liquid mixtures of carbon tetrachloride with benzene, toluene, 2-propanone, n-hexane, and n-octane.

Autor: Yi, S. C., Rowley, R. L.
Předmět:
Zdroj: Journal of Chemical Physics; 12/15/1987, Vol. 87 Issue 12, p7208, 6p
Abstrakt: Measurements of heats of transport are reported for binary liquid mixtures containing carbon tetrachloride and benzene, toluene, 2-propanone, n-hexane, or n-octane at 298 K and ambient pressure. Additionally, measurements were made at 308 K for carbon tetrachloride with benzene, toluene, and 2-propanone. The corresponding heat-mass Onsager coefficients are also reported, from which thermal diffusion ratios have been calculated based on Onsager reciprocity. These data will be used in a companion paper to report a modified Enskog method for correlation and prediction of heats of transport. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index