Infrared-microwave double resonance spectroscopy of the ν3 band of 11BF3 using a tunable diode laser.

Autor: Yamamoto, Satoshi, Kuchitsu, Kozo, Nakanaga, Taisuke, Takeo, Harutoshi, Matsumura, Chi, Takami, Michio
Předmět:
Zdroj: Journal of Chemical Physics; 8/15/1985, Vol. 83 Issue 4, p1444, 5p
Abstrakt: Pure rotational transitions in the ν3 state (E′) of 11BF3 due to vibrationally induced dipole moment are observed by infrared-microwave double resonance using a tunable diode laser. The induced dipole moment is estimated to be 0.04+0.02-0.01 D from the power broadening of the double resonance signals. The rotational constant C0 is determined experimentally by use of the observed infrared and microwave transitions to be 5161.4(6) MHz. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index