Overtone and hot-band assignments in the 2{ν3, ν6} levels of CHD3.

Autor: Roche, Ch., Champion, J.-P., Coy, S. L., Klaassen, J. J., Steinfeld, J. I., Valentin, A., Mizugai, Y., Johns, J. W. C.
Předmět:
Zdroj: Journal of Chemical Physics; 4/15/1994, Vol. 100 Issue 8, p5508, 11p
Abstrakt: Assignments have been carried out for the 2ν3/(ν3+ν6)/2ν6 (triad)←ground state overtone bands and the triad←ν3/ν6 hot-band system of CHD3. A vibrational extrapolation method, using correspondences between a spherical-tensor formalism and the more conventional description of symmetric-rotor spectra, was used to facilitate the assignment and analysis of these bands. The resulting assignments have been confirmed by time-resolved double-resonance measurements. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index