Autor: |
Herman, Zdenek, Henchman, Michael, Friedrich, Bretislav |
Předmět: |
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Zdroj: |
Journal of Chemical Physics; 10/1/1990, Vol. 93 Issue 7, p4916, 6p |
Abstrakt: |
A crossed-beam study of the reaction CH+4(CH4,CH3)CH+5 was carried out in the collision energy range 0.6–2.3 eV. Three distinct patterns were observed, which may be interpreted in terms of three competing mechanisms for CH+5 formation: proton stripping, H-atom pickup, and intermediate complex decomposition. The existence of a C2H+8 intermediate, stable towards dissociation, is suggested by the results. The relative weights of the three mechanisms were estimated as a function of collision energy. [ABSTRACT FROM AUTHOR] |
Databáze: |
Complementary Index |
Externí odkaz: |
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