| Autor: |
Kolbuszewski, Marcin, Gu, J.-P. |
| Předmět: |
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| Zdroj: |
Journal of Chemical Physics; 11/1/1995, Vol. 103 Issue 17, p7649, 2p |
| Abstrakt: |
Adiabatic and strictly diabatic potential curves were calculated for the two lowest electronic states of He22+. The diabatization procedure leads to a repulsive diabatic curve dissociating to He+ + He+ and a bound curve dissociating to He2+ + He, crossing at the internuclear distance of 1.55 bohr. The diabatic bound state has dissociation energy of 3.15 eV. The existence of a metastable potential well in the (adiabatic) X1Σg+ state of He22+ can be interpreted in terms of a strong interaction between the diabatic curves. © 1995 American Institute of Physics. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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