| Autor: |
Behm, Jane M., Arrington, Caleb A., Langenberg, Jon D., Morse, Michael D. |
| Předmět: |
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| Zdroj: |
Journal of Chemical Physics; 11/1/1993, Vol. 99 Issue 9, p6394, 15p |
| Abstrakt: |
Diatomic AlCu has been interrogated using resonant two-photon ionization spectroscopy in a supersonic expansion of helium. The ground state is shown to be X 1Σ+, deriving from the 3sAl23dCu10σ2 configuration, in agreement with theoretical predictions. The closed-shell nature of this molecule results in a low density of electronic states, allowing the chemical bonding and electronic structure to be investigated in detail. Five excited electronic states have been observed and characterized, leading to a potential energy diagram based solely on experimental results. Constants experimentally determined for AlCu include a ground state bond length (r0) of 2.3389±0.0004 Å, a dissociation energy, D0○, of 2.315±0.012 eV, and an ionization potential of 7.065±0.014 eV. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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