On the relation between the Wertheim’s two-density integral equation theory for associating fluids and Chandler–Silbey–Ladanyi integral equation theory for site–site molecular fluids.

Autor: Kalyuzhnyi, Yu. V., Cummings, P. T.
Předmět:
Zdroj: Journal of Chemical Physics; 3/1/1996, Vol. 104 Issue 9, p3325, 4p
Abstrakt: It is demonstrated that Chandler–Silbey–Ladanyi integral equation theory for the site–site molecular fluids is the limiting case of complete association of more general two-density integral equation theory for associating fluids developed by Wertheim. The analysis is presented for a site–site molecular system with any number and geometrical arrangement of the sites in the molecule and arbitrary type of the site–site pair interaction. © 1996 American Institute of Physics. [ABSTRACT FROM AUTHOR]
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