| Autor: |
Legon, A. C., Warner, H. E. |
| Předmět: |
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| Zdroj: |
Journal of Chemical Physics; 3/1/1993, Vol. 98 Issue 5, p3827, 6p, 2 Diagrams, 6 Charts, 1 Graph |
| Abstrakt: |
The weakly bound dimer H3P...Cl2 has been isolated in a pulsed jet by keeping the highly reactive components H3P and Cl2 separate until the point at which they expand into the evacuated Fabry–Pérot cavity of a pulsed-nozzle Fourier-transform microwave spectrometer. The rotational spectra of the three symmetric-top isotopomers H3P...35Cl 35Cl, H3P...35Cl 37Cl, and H3P...37Cl 35Cl detected in this way have been analyzed to give the ground-state spectroscopic constants B0, DJ, DJK, χ1(Cl), and χ2(Cl). Comparison of the dimer properties determined from the spectroscopic constants of H3P...Cl2 with those of the hydrogen-bonded dimer H3P...HCl indicates that charge transfer is not predominant in the interaction of PH3 and Cl2. Some parallels in the properties of B...Cl2 and B...HCl are discussed for B=PH3 and HF. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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