| Autor: |
Moore, D. S., Schmidt, S. C., Shaw, M. S., Johnson, J. D. |
| Předmět: |
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| Zdroj: |
Journal of Chemical Physics; 2/1/1989, Vol. 90 Issue 3, p1368, 9p |
| Abstrakt: |
Vibrational spectra of liquid nitrogen shock compressed to several high pressure/high temperature states were recorded using single-pulse multiplex coherent anti-Stokes Raman scattering. Vibrational frequencies, third-order susceptibility ratios, and linewidths are presented for the fundamental and several excited-state transitions. Vibrational frequencies were found to increase monotonically up to approx. 17.5 GPa single shock and approx. 30 GPa double shock. Above these pressures, the vibrational frequencies were observed to decrease with further increases in pressure. The decrease in vibrational frequency occurs in a pressure regime where the shocked nitrogen is becoming optically opaque. The consequence of the decrease in vibrational frequency on the Grüneisen mode gamma and its effect on the N2 equation of state is discussed. The transition intensity and linewidth data suggest that thermal equilibrium of the vibrational levels is attained in less than 10 ns at these high pressures and temperatures. Finally, the measured linewidths exhibit an almost linear dependence on shock temperature, and also suggest that the vibrational dephasing time has decreased to less than 1 ps at the highest pressures. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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