| Autor: |
Clary, David C., Sonnenfroh, David M. |
| Předmět: |
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| Zdroj: |
Journal of Chemical Physics; 2/1/1989, Vol. 90 Issue 3, p1686, 8p |
| Abstrakt: |
Calculations of cross sections for the charge transfer reaction Ar+(2P3/2)+N2(v=0, j) →Ar+N+2(v’=1, j’) are reported for thermal collision energies. A three-dimensional quantum-mechanical method is used in which separate rotational close-coupling calculations are performed for the Ar++N2(v=0)→Ar+N+2(v’=0) and Ar++N2(v=1) →Ar+N+2 (v’=1) channels, and the cross sections for the v=0→v’=1 channel are computed using a coupled channel-distorted wave Born approximation. Potential energy surfaces and couplings are taken from ab initio data. The predicted rotational product distributions for N+2 (v’=1, j’) agree fairly well with those measured in a molecular beam laser-induced fluorescence experiment. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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