Rydberg series of charge-transfer excitations: Cl and H in rare gas crystals.

Autor: Kunz, H., McCaffrey, J. G., Chergui, M., Schriever, R., Ünal, Ö., Stepanenko, V., Schwentner, N.
Předmět:
Zdroj: Journal of Chemical Physics; 8/1/1991, Vol. 95 Issue 3, p1466, 7p
Abstrakt: Rydberg series observed in the excitation spectra of Cl and H atoms isolated in the rare gas (Rg) crystals Kr and Xe are associated with the charge transfer species Cl-Rg+ and H-Rg+. The progressions originate from hole states of Rg+ which converge to the top of the rare gas valence band in an analogous manner to the convergence of conventional exciton states to the bottom of the conduction band. A model based on the effective mass approximation and a quantum defect concept predicted such progressions in Xe and Kr crystals and it is supported by the present results. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index