EXAFS study of solute–solute and solute–solvent interactions in acetonitrile solutions of CuBr2+nLiBr (n=0, 1, and 2).
| Autor: | Sano, Mitsuru, Maruo, Tetsuya, Yamatera, Hideo |
|---|---|
| Předmět: | |
| Zdroj: | Journal of Chemical Physics; 1/1/1986, Vol. 84 Issue 1, p66, 3p |
| Abstrakt: | The EXAFS studies of acetonitrile solutions of CuBr2, CuBr2+LiBr, and CuBr2+2LiBr have been carried out. The EXAFS spectra of Cu and Br edges were measured and transformed to radial distribution functions around Cu and Br ions, respectively. The curve-fitting analysis shows that the main species are [CuBr2(NCCH3)2], [CuBr3(NCCH3)]-, and [CuBr4]2- in the solutions containing Br- and Cu2+ in the Br-/Cu2+ ratio of 2, 3, and 4, respectively. [ABSTRACT FROM AUTHOR] |
| Databáze: | Complementary Index |
| Externí odkaz: |
|